Beilstein J. Nanotechnol.2017,8, 1375–1387, doi:10.3762/bjnano.8.139
, prevent the packing and self-assembly of the hydrocarbon chains. The smaller film thickness of 7 is attributed to the specific coordination mode of the coligand. Results of preliminary transport measurements utilizing rolled-up devices are also reported.
Keywords: ambidentateligands; chemisorption; gold
over a monolayer of chemisorbed molecules of 2 previously synthesized on a thin gold film deposited onto a silicon pillar (for details, see Supporting Information File 1).
Ambidentateligands with soft (–SH, –PPh2) and hard (–CO2H) donor functions.
ORTEP (left) and van der Waals representations (right
PDF
Scheme 1:
Structure of the dinuclear complexes [M2L(μ-L’)](ClO4) and representation of the structure of compl...